Category Archives: Year 2015 Issue 7

Analysis of the composite materials having a structure of the mineral fibers based on the non-invasive spectroscopic methods

Analysis of the composite materials having a structure of the mineral fibers based on the non-invasive spectroscopic methods ŚMISZEK-LINDERT W., BAJOREK A., KUBACKI J.

Please cite as: CHEMIK 2015, 69, 7, 411–418 Chemical composition of glass wool and stone wool has been investigated. Researches were carried out by using two analytical techniques, X-ray fluorescence analysis (XRF) and X-ray photoelectron spectroscopy (XPS). The both methods are non-destructive. It was observed that composition of the glass wool and stone wool...
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Structural studies of cyclic β-amino ketons using computational and NMR methods

Structural studies of cyclic β-amino ketons using computational and NMR methods SIDOROWICZ K., ŁAŹNY R.

Please cite as: CHEMIK 2015, 69, 7, 401–410 Because of pyramidal configuration of the nitrogen atom, tropanes, granatanes, and their derivatives can exist in two stereoisomeric forms, in which N-substituents can be oriented axial or equatorial with respect to the piperidone ring. The N-invertomer stereochemistry of N-substituted bicyclic β-amino ketones has been investigated using experimental, and theoretical methods, such as NMR, microwave...
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Conjugated nitroalkenes as components of nonconcerted Diels-Alder reactions – recent studies

Conjugated nitroalkenes as components of nonconcerted Diels-Alder reactions – recent studies JASIŃSKA E., DRESLER E. ŁAPCZUK-KRYGIER A., KĄCKA A., NOWAKOWSKA-BOGDAN E., JASIŃSKI R.

Please cite as: CHEMIK 2015, 69, 7, 395–400 In the publication the recent progres concerning non-concerted Diels-Alder reactions with conjugated nitroalkenes has been discussed. Keywords: Nitroalkenes , Diels-Alder reaction, cycloaddition reaction, mechanizm Read more in pdf pdf-icon...
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Vitrimers – the miracle polymer materials combining the properties of glass and plastic?

Vitrimers – the miracle polymer materials combining the properties of glass and plastic? JUROWSKA A., JUROWSKI K.

Please cite as: CHEMIK 2015, 69, 7, 389–394 Vitrimers are a new class of polymer materials invented by Ludwik Leibler (Polish-born chemist) and his co-workers from France. This class of polymers has highly desirable properties, combining reparability and malleability at high temperatures with insolubility. These compounds can be understood as strong organic glass formers with covalent networks that are able to...
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Electrodeposition Coatings – the perfect symbiosis of water/electro/paint chemistry

Electrodeposition Coatings – the perfect symbiosis of water/electro/paint chemistry BROCK T.

Please cite as: CHEMIK 2015, 69, 7, 383–388 Electrodeposition coatings are – since 5 decades – the basis for good corrosion protection of industrial goods, especially known worldwide for the production of passenger cars. In contrast to the application of most other paints the workpiece is dipped into a colloidal solution of the waterborne paint. A strong electric current, followed by water electrolysis, causes a pH-shift at...
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Ion-selective electrodes – classical systems and new ideas

Ion-selective electrodes – classical systems and new ideas MAKSYMIUK K., MICHALSKA A.

Please cite as: CHEMIK 2015, 69, 7, 378–382 The article concerns trends in development of ion-selective electrodes used in potentiomeric analysis, it shows typical practical solutions and describes main trends of research concerning this group of sensors, oriented both to construction simplification and improvement of analytical parameters. New analytical advantages, achieved under conditions of galvanostatic polarization, were also described. Keywords: Ion-selective electrodes, potentiometry, construction simplification, detection limit...
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