Technologies of syntheses of fluorofunctional silicon compounds
MACIEJEWS KI H., KARASI EWI CZ J.

Please cite as: CHEMIK 2012, 66, 7, 735-741

A versatile method was presented for synthesis of different fluorofunctional organosilicon derivatives (silanes, polysiloxanes and silsesquioxanes) based on hydrosilylation of allyl-fluoroalkyl ethers. The process of hydrosilylation was catalysed by rhodium siloxide complex [{Rh(?-OSiMe3)(cod)}2] immobilised in ionic liquid. Studies on optimisation of the above process were performed and a brief foredesign was worked out.

Keywords: fluorocarbosilanes, hydrosilylation, rhodium complexes, ionic liquids